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Mediated electrochemical oxidation systems and apparatus for destroying materials, including clothing and instruments, contaminated biological, organic and inorganic materials, clothing and instruments, and rendering contaminated equipment and waste materials free of biological, organic, inorganic and radioactive materials, composed of cabinets, housings, cases, electrolytic cells, chambers, reservoirs, pumps and membranes, sensors, coolers, heaters, temperature controllers and process controllers; apparatus for separating electrolytes into anolytes and catholytes with semi-permeable membranes and applying electric energy to the catholytes in the electrolytes, and exposing materials to mediated electrochemical strong oxidizing anolytes and enhancing the process with ultrasonic, ultraviolet and other energy applications to the anolyte and treated materials, and electrolytes and additives for use in the electrolytic cells, sold together as a unit therewith